Anomalous exothermic and endothermic data observed by Nano-Ni-composite samples
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This is an experimental paper summarizing the observations of anomalous data on excess heat, D(H)-loading and abrupt desorption with endothermic heat sink in Ni-nano-composite samples under D(H)-gas charging at both room and elevated temperatures, done by Kobe-Technova group in 2012-2013. Referring to our JCF12 paper (Y. Miyoshi et al., JCF-12-1) on Pd1Ni7/ZrO2 samples, experimental procedure and results reported for Ni/ZrO2, Cu0.21Ni0.21/ZrO2 and Cu0.08Ni0.36/ZrO2 samples (partially reported in our JCF13-15 paper by Sakoh et al.) will be summarized. We have reanalyzed time-dependent data for speculating heat releasing mechanisms during the long (several weeks) lasted phase of D(H)-loading-into-nano-metal. It seems that competing process of D(H)-gas sorption and desorption at the surface of nano-powders would be attributed to the mechanism. Burst-like heat peaks of η-values (in unit of eV per D(H)-take-in/out) were observed with anomalously high values reaching 600 eV/H-sorption, and with smaller [eta]-values for isotopic Dsorption than H-sorption, at 573K. Integrated heat values for several-week runs were reached at the levels of ca. 800eV/atom-Ni for Cu0.08Ni0.36/ZrO2 samples, which were about 10 times larger than those of Ni/ZrO2 samples and about 4 times larger than those of Cu0.21Ni0.21/ZrO2 samples, at temperatures of 523 to 573K.