Browsing 2007 Dissertations (MU) by Title "Phosphinimines as potential technetium environmental sensors"
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Phosphinimines as potential technetium environmental sensors
(University of Missouri--Columbia, 2007)Phosphinimines, R₃P=NSiMe₃, undergo hydrolysis to form the phosphiniminiumcation, R₃P=NH₂+, which forms the ion pair [R₃P=NH₂+][X-] in the presence of an anion.Preliminary studies show that in the presence of TcO₄-, ...