Anion and solvent influences on the self-assembly of copper(I) coordination solids

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Anion and solvent influences on the self-assembly of copper(I) coordination solids

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dc.contributor.advisor Keller, S. W. (Steven W.) en
dc.contributor.author Knight, Douglas A., 1957- en_US
dc.date.accessioned 2010-01-06T21:20:22Z
dc.date.available 2010-01-06T21:20:22Z
dc.date.issued 2005 en_US
dc.date.submitted 2005 Fall en
dc.identifier.other KnightD-120705-D3694 en_US
dc.identifier.uri http://hdl.handle.net/10355/4187
dc.description The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. en_US
dc.description Title from title screen of research.pdf file viewed on (November 8, 2006) en_US
dc.description Includes bibliographical references. en_US
dc.description Vita. en_US
dc.description Thesis (Ph. D.) University of Missouri-Columbia 2005. en_US
dc.description Dissertations, Academic -- University of Missouri--Columbia -- Chemistry. en_US
dc.description.abstract The investigation of solvent and anion influences on the self-assembly of copper(I) coordination solids are presented. As these extended solids vary in structural design as reactions conditions are varied, both those particular structural variances and the reaction conditions involved will be discussed. This presentation will be divided into four major sections. The first section covers an in-depth look at those structural variances found among the copper(I) coordination solids synthesized using 4,4'-bipyridine with refined synthesis and related structures. This entire system is thoroughly examined in order to identify all possible structural variances resulting from the implementation of a specific set of reaction variables, specifically the identity of both anion and reaction solvent used. The second and third parts will look closer at the self-assembly reaction mechanism as synthetic intermediate structures are presented and analyzed in relation to the above-mentioned structures. Each structure presented offers information in regards to the role the anion or solvent play in the self-assembly reactions The final section deals with similar reactions using the pyrimidine ligand. Several structures presented here suggests that anion templation plays a major role in the extended solids formation. This section concludes with a practical application of these materials as a study of selective anion exchange with a large cavity Cu(I) coordination solid is presented. en_US
dc.language.iso en_US en_US
dc.publisher University of Missouri--Columbia en_US
dc.relation.ispartof 2005 Freely available dissertations (MU) en_US
dc.subject.lcsh Copper -- Reactivity en_US
dc.subject.lcsh Copper -- Structure-activity relationships en_US
dc.subject.lcsh Porous materials en_US
dc.subject.lcsh Anion separation en_US
dc.title Anion and solvent influences on the self-assembly of copper(I) coordination solids en_US
dc.type Thesis en_US
thesis.degree.discipline Chemistry en_US
thesis.degree.grantor University of Missouri--Columbia en_US
thesis.degree.name Ph. D. en_US
thesis.degree.level Doctoral en_US
dc.identifier.merlin .b57090403 en_US
dc.relation.ispartofcommunity University of Missouri-Columbia. Graduate School. Theses and Dissertations. Dissertations. 2005 Dissertations


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