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dc.contributor.advisorKeller, S. W. (Steven W.)eng
dc.contributor.authorKnight, Douglas A., 1957-eng
dc.date.issued2005eng
dc.date.submitted2005 Falleng
dc.descriptionThe entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file.eng
dc.descriptionTitle from title screen of research.pdf file viewed on (November 8, 2006)eng
dc.descriptionIncludes bibliographical references.eng
dc.descriptionVita.eng
dc.descriptionThesis (Ph. D.) University of Missouri-Columbia 2005.eng
dc.descriptionDissertations, Academic -- University of Missouri--Columbia -- Chemistry.eng
dc.description.abstractThe investigation of solvent and anion influences on the self-assembly of copper(I) coordination solids are presented. As these extended solids vary in structural design as reactions conditions are varied, both those particular structural variances and the reaction conditions involved will be discussed. This presentation will be divided into four major sections. The first section covers an in-depth look at those structural variances found among the copper(I) coordination solids synthesized using 4,4'-bipyridine with refined synthesis and related structures. This entire system is thoroughly examined in order to identify all possible structural variances resulting from the implementation of a specific set of reaction variables, specifically the identity of both anion and reaction solvent used. The second and third parts will look closer at the self-assembly reaction mechanism as synthetic intermediate structures are presented and analyzed in relation to the above-mentioned structures. Each structure presented offers information in regards to the role the anion or solvent play in the self-assembly reactions The final section deals with similar reactions using the pyrimidine ligand. Several structures presented here suggests that anion templation plays a major role in the extended solids formation. This section concludes with a practical application of these materials as a study of selective anion exchange with a large cavity Cu(I) coordination solid is presented.eng
dc.identifier.merlin.b57090403eng
dc.identifier.oclc75405617eng
dc.identifier.otherKnightD-120705-D3694eng
dc.identifier.urihttp://hdl.handle.net/10355/4187eng
dc.languageEnglisheng
dc.publisherUniversity of Missouri--Columbiaeng
dc.relation.ispartofcollectionUniversity of Missouri-Columbia. Graduate School. Theses and Dissertations.eng
dc.subject.lcshCopper -- Reactivityeng
dc.subject.lcshCopper -- Structure-activity relationshipseng
dc.subject.lcshPorous materialseng
dc.subject.lcshAnion separationeng
dc.titleAnion and solvent influences on the self-assembly of copper(I) coordination solidseng
dc.typeThesiseng
thesis.degree.disciplineChemistry (MU)eng
thesis.degree.grantorUniversity of Missouri--Columbiaeng
thesis.degree.levelDoctoraleng
thesis.degree.namePh. D.eng


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