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Organo nickel and platinum chemistry at the edge of corannulene
(University of Missouri--Columbia, 2007)
[ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI AT AUTHOR'S REQUEST.] Corannulene (C[subscript 20]H[subscript 10]), a polycyclic aromatic hydrocarbon (PAH) is a bowl shaped fullerene fragment. This work involves investigations ...
Alkene-oxo and alkene-alkene coupling on Pt(II)
(University of Missouri--Columbia, 2005)
Tetranuclear Pt(II) oxo-complex [(COD)4Pt4([mu]3-O)2Cl2](BF4)2 (1) (COD = 1,5- cyclooctadiene) was found to readily react with a variety of alkenes (ethylene, norbornene, propylene and cyclopentene). The most significant ...
Alkene oxidation by platinum (II) oxo/hydroxo complexes
(University of Missouri--Columbia, 2011)
The facile reaction between tetranuclear Pt-oxo complex [(COD)4Pt4([mu]2-O)2Cl2]2[BF4]2 (1) and norbornene (NB) yields the stable platinaoxetane [(COD)2Pt2(OC7H10)Cl][BF4] (2) in quantitative yield. A rapid reaction between ...
Bromine photoelimination from organoplatinum(IV) complexes
(University of Missouri--Columbia, 2014)
With burgeoning population growth and widespread economic development world energy consumption is constantly on the rise. Currently most of our energy requirements are met through fossil fuels which are non-renewable. The ...
Chlorine and singlet oxygen photoelimination from organoplatinum(IV) complexes
(University of Missouri--Columbia, 2015)
[ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI AT AUTHOR'S REQUEST.] Solar energy is the most promising carbon neutral energy source for the future. Splitting of simple molecules like HX (X = Cl, Br) has become an ...
Synthesis, characterization and photophysical studies of cyclometalated Au(III) complexes
(University of Missouri--Columbia, 2015)
We report here a series of room temperature emissive biphenyl cyclometalated gold (III) diethyl dithiocarbamate complexes (DEDT) having H, CF3, OMe and tBu substitutions on the biphenyl moiety. Synthesis of these complexes ...
Photochemistry of platinum and iridium compexes relevant to solar energy conversion and storage
(University of Missouri--Columbia, 2014)
Sythesis, characterization and reactivity of platinum (II) peroxo, alkoxide and triflate compunds
(University of Missouri--Columbia, 2012)
[ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI AT AUTHOR'S REQUEST.] The chemistry of a collection of platinum(II) compounds, including peroxo, alkoxide and triflate compounds, were synthesized and studied. This involved ...
Synthesis, characterisation photophysical and DFT studies of 2,2'-diphenylenegold(III) diethyldithiocarbamate
(University of Missouri--Columbia, 2012)
[ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI AT REQUEST OF AUTHOR.] Cyclometalated gold(III) complexes have been demonstrated to show electroluminescence properties and have been employed as electrophosphorescent ...
Synthesis and photochemistry of PT (IV) hydroxo complexes
(University of Missouri--Columbia, 2015)
Global energy consumption and the production of clean renewable energy have become greater challenges. Sunlight-induced splitting of water into H2 and O2 is one of the leading strategies to achieve clean and renewable ...