Browsing Chemistry electronic theses and dissertations (MU) by Title "1,5-hydride shift of alkenyl sulfoximine/[4+3] cycloaddition and ring opening/novel hydrazine synthesis from Tröger's base analogues"
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1,5-hydride shift of alkenyl sulfoximine/[4+3] cycloaddition and ring opening/novel hydrazine synthesis from Tröger's base analogues
(University of Missouri--Columbia, 2012)Three synthetic methodologies are studied in details in this dissertation. For 1,5-hydride shift of alkenyl sulfoximine methodology, the reaction mechanism was studied using deuterium labeling. An uncommon 6-endo-trig ...