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dc.contributor.advisorKeller, S. W. (Steven W.)eng
dc.contributor.authorBockhold, Steveneng
dc.date.issued2008eng
dc.date.submitted2008 Springeng
dc.descriptionThe entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file.eng
dc.descriptionTitle from title screen of research.pdf file (viewed on June 2, 2009).eng
dc.descriptionVita.eng
dc.descriptionThesis (Ph. D.) University of Missouri-Columbia 2008.eng
dc.description.abstractThe use of solid-solid reactions in the development of one-, two-, and three dimensional Cu(I) coordination networks are discussed. The solid-solid reactions were monitored by a variety of instrumental techniques to achieve a better picture of the solid-solid reaction mechanism. The crystalline reagents led to crystalline products with no amorphous phase. The nitrogen containing bridging ligands, 4,7-phenanthroline, 4,4'- dipyridyl, and trans-1,2-bis(4-pyridy1)ethylene in addition to 1,3-dithiane were used in the formation of these networks. The resultant crystalline compounds were compared to the solution-based products, showing that on average the same product was formed. Through the bridging ligands and a change in the coordinated solvent, the ultimate goal of showing how these solid-solid reactions could be expanded to cover a large array of reagents was accomplished.eng
dc.description.bibrefIncludes bibliographical referenceseng
dc.identifier.merlinb68586784eng
dc.identifier.oclc368151417eng
dc.identifier.urihttps://doi.org/10.32469/10355/5612eng
dc.identifier.urihttps://hdl.handle.net/10355/5612
dc.languageEnglisheng
dc.publisherUniversity of Missouri--Columbiaeng
dc.relation.ispartofcommunityUniversity of Missouri--Columbia. Graduate School. Theses and Dissertationseng
dc.rightsOpenAccess.eng
dc.rights.licenseThis work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivs 3.0 License.
dc.subject.lcshCoppereng
dc.subject.lcshCoordination compoundseng
dc.subject.lcshChemical reactionseng
dc.subject.lcshEnvironmental chemistry -- Industrial applicationseng
dc.titleCopper (I) coordination networks synthesized with solid-solid reactionseng
dc.typeThesiseng
thesis.degree.disciplineChemistry (MU)eng
thesis.degree.grantorUniversity of Missouri--Columbiaeng
thesis.degree.levelDoctoraleng
thesis.degree.namePh. D.eng


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