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dc.contributor.advisorHarmata, Michael, 1959-eng
dc.contributor.authorRayanil, Kanok-on, 1976-eng
dc.date.issued2006eng
dc.date.submitted2006 Falleng
dc.descriptionThe entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file.eng
dc.descriptionTitle from title screen of research.pdf file (viewed on August 10, 2007)eng
dc.descriptionIncludes bibliographical references.eng
dc.descriptionVita.eng
dc.descriptionThesis (Ph. D.) University of Missouri-Columbia 2006.eng
dc.descriptionDissertations, Academic -- University of Missouri--Columbia -- Chemistry.eng
dc.description.abstract[ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI AT AUTHOR'S REQUEST.] The sequential alkylation of Tröger's base was developed for the synthesis of symmetric dialkylation analogs. The products from this reaction were obtained in reasonable yields with regio- and stereoselectivity. The transformation of the products into chiral amines including the metal ion interaction studies of the new chiral ligands was investigated. A novel intramolecular cycloaddition of cyclopentadienone was developed by using molecules that had two cyclopentadienone units. It was demonstrated that the reaction occurs at room temperature or below to produce the dimer adducts in endo-selectivity. A variety of different substituted dimers containing an angular triquinane unit were prepared in relatively low yields. The coupling reaction of compounds incorporating an aryl ring processing a bromide ortho to an electron efficient alkene with methyl phenylsulfoximine was examined. This reaction provided the corresponding sulfoximines in high yields and also gave 2,1- benzothiazines in some cases. The intramolecular, stereoselective Micheal addition reaction of sulfoximine carbanions to compounds containing electron deficient alkenes was studied.eng
dc.identifier.merlinb59291710eng
dc.identifier.oclc163600231eng
dc.identifier.urihttps://hdl.handle.net/10355/5861
dc.identifier.urihttps://doi.org/10.32469/10355/5861eng
dc.languageEnglisheng
dc.publisherUniversity of Missouri--Columbiaeng
dc.relation.ispartofcollectionUniversity of Missouri-Columbia. Graduate School. Theses and Dissertationseng
dc.rightsAccess is limited to the campus of the University of Missouri--Columbia.eng
dc.subject.lcshRing formation (Chemistry)eng
dc.subject.lcshCyclopentadieneeng
dc.subject.lcshBenzothiazineeng
dc.titleStudies of the chemistry of Tröger's base, cyclopentadienones, and 2,1-benzothiazineseng
dc.typeThesiseng
thesis.degree.disciplineChemistry (MU)eng
thesis.degree.grantorUniversity of Missouri--Columbiaeng
thesis.degree.levelDoctoraleng
thesis.degree.namePh. D.eng


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