Kinetics, mass transfer, and mass re-equilibrium for arsenate adsorption on iron oxide-based carbons
Abstract
[ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI AT AUTHOR'S REQUEST.] Removal of arsenic (As) from drinking water sources is much needed worldwide, and small water treatment systems, such as point-of-use (POU) treatment, could be an effective solution for residential applications. Adopting existing removal technologies that are successful in large-scale treatment to small-scale units, however, is rather ineffective due to the short hydraulic residence time in small water treatment systems. … The Freundlich isotherm can fit experimental data well: a crossover point for the two fitted Freundlich isotherms was observed and nano-FeAC had higher adsorption plateau. Furthermore, we demonstrated that due to the MRE process, a pseudo-equilibrium of FeMC was altered to another steady state by an in situ extraction with nano-FeAC in both batch and column systems. The overall inter-medium mass transfer resulted in both improved adsorption densities obtained by batch tests and a large bed volume prior to the 10 [mu]g As/L breakthrough at a short empty bed contact time (0.85 min).
Degree
Ph. D.
Thesis Department
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