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dc.contributor.authorHerwig, K. W.
dc.contributor.authorMatthies, Blake E. (Blake Edward), 1968-
dc.contributor.authorTaub, Haskell
dc.date.issued1995-10eng
dc.descriptionURL:http://link.aps.org/doi/10.1103/PhysRevLett.75.3154 DOI:10.1103/PhysRevLett.75.3154en_US
dc.description.abstractNeutron diffraction patterns of dotriacontane ( n-C32D66) monolayers adsorbed on an exfoliated graphite substrate from a heptane ( n-C7D16) solution reveal striking differences in the molecular orientation, lattice constant, and coherence length from those of the same monolayer adsorbed from the gas phase. Neither n-C32D66 monolayer phase appears to be fully consistent with Groszek's model of n-alkane registry on the graphite (0001) surface. A reversible transformation between the two monolayer phases can be induced by adding as little as a monolayer of the heptane solvent.en_US
dc.description.sponsorshipAcknowledgement is made to the u.S. National Science Foundation under Grant No. DMR-9314235, the Missouri University Research Reactor, and to the donors of The Petroleum Research Fund, administered by the ACS, for partial support of this research.en_US
dc.identifier.citationPhys. Rev. Lett. 75, 3154-3157 (1995)en_US
dc.identifier.issn0031-9007
dc.identifier.urihttp://hdl.handle.net/10355/8771
dc.publisherAmerican Physical Societyen_US
dc.relation.ispartofMissouri Research Reactor publications (MU)en
dc.relation.ispartofcommunityUniversity of Missouri-Columbia. University of Missouri Research Reactor Center
dc.subjectmolecular orientationen_US
dc.subject.lcshNeutrons -- Diffractionen_US
dc.subject.lcshAdsorptionen_US
dc.subject.lcshMonomolecular layersen_US
dc.titleSolvent Effects on the Monolayer Structure of Long n-Alkane Molecules Adsorbed on Graphiteen_US
dc.typeArticleen_US


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