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    Anomalous layering of Fe(CO)5 adsorbed on graphite

    Dennison, J. R.
    Taub, Haskell
    Hansen, Flemming Y.
    Shechter, H.
    Brener, R.
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    [PDF] AnomalousLayeringFeCO5Adsorbed.pdf (881.1Kb)
    Date
    1989
    Format
    Article
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    Abstract
    Synchrotron x-ray diffraction experiments reveal the adsorption of iron pentacarbonyl [Fe(CO)5] on graphite basal-plane surfaces to be an extreme example of incomplete wetting in which only one solid layer of film coexists with bulk particles. Upon heating through the monolayer melting point, the amount of coexisting bulk solid first increases and then decreases. This anomalous layering behavior has not been observed in other systems exhibiting incomplete wetting, and we suggest that it is related to the steric properties of the Fe(CO)5 molecule.
    URI
    http://hdl.handle.net/10355/8817
    Citation
    Phys. Rev. B 37, 2266-2269 (1988)
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    • Physics and Astronomy publications (MU)

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