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Anomalous layering of Fe(CO)5 adsorbed on graphite

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http://hdl.handle.net/10355/8817
dc.contributor.authorDennison, J. R.eng
dc.contributor.authorTaub, Haskelleng
dc.contributor.authorHansen, Flemming Y.eng
dc.contributor.authorShechter, H.eng
dc.contributor.authorBrener, R.eng
dc.date.issued1989eng
dc.descriptionURL:http://link.aps.org/doi/10.1103/PhysRevB.37.2266 DOI:10.1103/PhysRevB.37.2266eng
dc.description.abstractSynchrotron x-ray diffraction experiments reveal the adsorption of iron pentacarbonyl [Fe(CO)5] on graphite basal-plane surfaces to be an extreme example of incomplete wetting in which only one solid layer of film coexists with bulk particles. Upon heating through the monolayer melting point, the amount of coexisting bulk solid first increases and then decreases. This anomalous layering behavior has not been observed in other systems exhibiting incomplete wetting, and we suggest that it is related to the steric properties of the Fe(CO)5 molecule.eng
dc.description.sponsorshipThis work was partially suported U.S. National Science Foundation Grants No. DMR-79-05958, No. DMR-83-04366, and No. DMR-87-04938; Israel-U.s. Binational Science Foundation Grant No. 2687; and u.S. Department of Energy Grant No. DE-FG02-85ER45183 of the MATRIX Participating Research Team.eng
dc.identifier.citationPhys. Rev. B 37, 2266-2269 (1988)eng
dc.identifier.issn1098-0121eng
dc.identifier.urihttp://hdl.handle.net/10355/8817eng
dc.languageEnglisheng
dc.publisherAmerican Physical Societyeng
dc.relation.ispartofcollectionUniversity of Missouri--Columbia. College of Arts and Sciences. Department of Physics and Astronomy. Physics and Astronomy publicationseng
dc.subjectstructure of clean surfaceseng
dc.subject.lcshPhase transformations (Statistical physics)eng
dc.subject.lcshCritical phenomena (Physics)eng
dc.titleAnomalous layering of Fe(CO)5 adsorbed on graphiteeng
dc.typeArticleeng


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