Formation of water channels in the crystalline hydrates of macrocyclic compounds [dataset]
Metadata[+] Show full item record
RSP and matrix zip files contain .sfrm files that have both the photographic data and metadata desicribing the instrument, readable with scientific software. The work zip file subfolder contains a .p4p file generated after data reduction.Abstract from published article: Crystalline hydrates of macrocyclic compounds such as pyroagllolarenes (PgCs) and resorcinarenes (RsCs) are rare owing to their lower water solubility. Functionalization of these macrocyclic compounds is an affordable way to enhance water solubility. However, functionalization also encounters the formation of multiple conformers and subsequent difficulty in purification of the product. Herein, four novel crystalline hydrates of functionalized PgCs and RsCs were synthesized. Formation of water channels and the effects of intermolecular interactions on the physical properties of these novel hydrates are discussed.
Table of Contents
RSP07242017-01 (370 .sfrm files) -- matrix-01 (12 .sfrm files) -- RSP07242017-02 (370 .sfrm files) -- matrix-02 (12 .sfrm) -- RSP07242017-03 (370 .sfrm files) -- RSP07242017-xa (3 .sfrm files) -- matrix-xa (2 .sfrm files) -- work (40 files of various types) + history folder (1 file).
Patil, R. S.; Zhang, C.; Sikligar, K.; Baker, G. A.; Atwood, J. L. "Formation of water channels in the crystalline hydrates of macrocyclic compounds." Chem. Eur. J. 2018, 24, 3299-3304. DOI: 10.1002/chem.201705609.
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivs 3.0 License.