Orientational ordering of commensurate Fe(CO)5 monolayers on graphite

MOspace/Manakin Repository

Breadcrumbs Navigation

Orientational ordering of commensurate Fe(CO)5 monolayers on graphite

Please use this identifier to cite or link to this item: http://hdl.handle.net/10355/8840

[+] show full item record


Title: Orientational ordering of commensurate Fe(CO)5 monolayers on graphite
Author: Wang, R.; Taub, Haskell; Shechter, H.; Brener, R.; Suzanne, J.
Date: 1983-05-01
Publisher: American Physical Society
Citation: Phys. Rev. B 27, 5864-5867 (1983)
Abstract: Elastic neutron diffraction and Mössbauer spectroscopy have been used to study the structure, orientational-disordering (OD) transition, and melting of an Fe(CO)5 submonolayer adsorbed on Grafoil. The OD transition occurs between 150 and 167 K from a two-sublattice (√7×√21) structure to a nearly (√7×√7) phase in which the molecules are believed to rotate about the surface normal. Mössbauer spectra exhibit a more abrupt variation with temperature near melting at 170 K than through the OD transition.
URI: http://hdl.handle.net/10355/8840
ISSN: 1098-0121

This item appears in the following Collection(s)

[+] show full item record