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Conformational and Structural Determinations of Substituted Four and Five Membered Rings by Infrared, Raman, and Microwave Spectral Studies
(2014)
Studies of the structure and conformational stabilities of molecules have become
increasingly important due in part to advances in the fields of biochemistry and nanochemistry.
Specifically the conformation of organoamines ...
Raman, Infrared and Microwave Spectra, Conformational Stability, R₀ Structural Parameters and Vibrational Assignments of Some Organoamines, Organophosphines, Alcohols And Substituted Four And Five Membered Rings
(2014)
with enthalpy difference relative to Tt for Tg of 79 ± 9 cm⁻¹ (0.9 ± 0.1 kJ/mol); for Gg of 91 ± 26 cm⁻¹ (1.08 ± 0.3 kJ/mol); for Gg' of 135 ± 21 cm⁻¹ (1.61 ± 0.2 kJ/mol); for Gt of 143 ± 11 cm⁻¹ (1.71 ± 0.1 kJ/mol). For 2-cyanoethylamine, the enthalpy...
Conformational stability of some silanes and amines from temperature dependent Infrared spectra of rare as solutions, r₀ structural parameters, ab initio calculations, and vibrational assignments
(University of Missouri--Kansas City, 2012-06-12)
,2-difluoroethylamine, the enthalpy differences among the most stable Tt conformer and the second stable conformer, Gg, is 83 ± 8 cm-1 (0.99 ± 0.10 kJ mol-1), the third stable conformer, Gt, is 235 ± 11 cm-1 (2.81 ± 0.13 kJ mol-1). For pyrrolidine, the envelope...